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Pentaamina(dinitrogen)rutenium(II) klorida - Riwayat revisi
2026-09-16T03:51:51Z
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Maintenance script: Presentation V4: sitasi, referensi, Math, Wikimedia Commons, dan atribusi
2026-08-30T04:10:00Z
<p>Presentation V4: sitasi, referensi, Math, Wikimedia Commons, dan atribusi</p>
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<td colspan="2" style="background-color: #fff; color: #202122; text-align: center;">← Revisi sebelumnya</td>
<td colspan="2" style="background-color: #fff; color: #202122; text-align: center;">Revisi per 30 Agustus 2026 04.10</td>
</tr><tr><td colspan="2" class="diff-lineno" id="mw-diff-left-l1">Baris 1:</td>
<td colspan="2" class="diff-lineno">Baris 1:</td></tr>
<tr><td class="diff-marker" data-marker="−"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div>'''Pentaamina(dinitrogen)rutenium(II)''' klorida adalah suatu [[senyawa anorganik]] dengan rumus [Ru(NH<sub>3</sub>)<sub>5</sub>(N<sub>2</sub>)]Cl<sub>2</sub>. Ia berupa padatan hampir putih, tetapi larutannya berwarna kuning. Kompleks kationnya memiliki makna historis sebagai senyawa pertama dengan N terikat pada pusat logam. [Ru(NH<sub>3</sub>)<sub>5</sub>(N<sub>2</sub>)]<sup>2+</sup> mengadopsi struktur oktahedral dengan simeteri C<sub>4v</sub>.</div></td><td class="diff-marker" data-marker="+"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div><ins style="font-weight: bold; text-decoration: none;">[[File:RuA5N2.png|thumb|right|280px|RuA5N2]]</ins></div></td></tr>
<tr><td colspan="2" class="diff-side-deleted"></td><td class="diff-marker" data-marker="+"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div> </div></td></tr>
<tr><td colspan="2" class="diff-side-deleted"></td><td class="diff-marker" data-marker="+"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>'''Pentaamina(dinitrogen)rutenium(II)''' klorida adalah suatu [[senyawa anorganik]] dengan rumus [Ru(NH<sub>3</sub>)<sub>5</sub>(N<sub>2</sub>)]Cl<sub>2</sub>. Ia berupa padatan hampir putih, tetapi larutannya berwarna kuning. Kompleks kationnya memiliki makna historis sebagai senyawa pertama dengan N terikat pada pusat logam.<ins style="font-weight: bold; text-decoration: none;"><ref>[https://id.wikipedia.org/w/index.php?title=Pentaamina%28dinitrogen%29rutenium%28II%29+klorida&oldid=26994809 sumber pada Wikipedia bahasa Indonesia]</ref><ref>Senoff, C.V. (1990) "The discovery of [Ru(NH 3 )5NN 2 ] 2+ : A case of serendipity and the scientific method" ''Journal of Chemical Education'', volume 67: 368.</ref> </ins>[Ru(NH<sub>3</sub>)<sub>5</sub>(N<sub>2</sub>)]<sup>2+</sup> mengadopsi struktur oktahedral dengan simeteri C<sub>4v</sub>.<ins style="font-weight: bold; text-decoration: none;"><ref>Fergusson, J. E.; Love, J. L.; Robinson, W. T. (1972) "The Crystal and Molecular Structure of Dinitrogenpentaammineosmium(II) Chloride, [Os(NH 3 ) 5 N 2 ]Cl 2 , and Related Ruthenium Complexes" ''Inorg. Chem.'', 11, pp. 1662–1666.</ref></ins></div></td></tr>
<tr><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><br></td><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><br></td></tr>
<tr><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>== Preparasi dan sifat ==</div></td><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>== Preparasi dan sifat ==</div></td></tr>
<tr><td class="diff-marker" data-marker="−"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div>Pentaamine(nitrogen)ruthenium(II) klorida disintesis dalam larutan air dari pentaaminaklororuthenium(III) klorida, [[natrium azida]], dan [[asam metanasulfonat]]:</div></td><td class="diff-marker" data-marker="+"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>Pentaamine(nitrogen)ruthenium(II) klorida disintesis dalam larutan air dari pentaaminaklororuthenium(III) klorida, [[natrium azida]], dan [[asam metanasulfonat]]:<ins style="font-weight: bold; text-decoration: none;"><ref>Allen, A. D., Bottomley, F., Harris, R. O., Reinsalu, V. P., Senoff, C. V. "Pentaammine(Nitrogen)Ruthenium(II) Salts and Other Ammines of Ruthenium" ''Inorganic Syntheses'', 2007, volume 12, pp. 2-8.</ref></ins></div></td></tr>
<tr><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>:[Ru(NH<sub>3</sub>)<sub>5</sub>Cl]Cl<sub>2</sub> + NaN<sub>3</sub> → [Ru(NH<sub>3</sub>)<sub>5</sub>N<sub>2</sub>]Cl<sub>2</sub> + ...</div></td><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>:[Ru(NH<sub>3</sub>)<sub>5</sub>Cl]Cl<sub>2</sub> + NaN<sub>3</sub> → [Ru(NH<sub>3</sub>)<sub>5</sub>N<sub>2</sub>]Cl<sub>2</sub> + ...</div></td></tr>
<tr><td class="diff-marker" data-marker="−"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div>Jika digunakan secara ''in situ'', kation dapat dibuat dengan mudah dari ruthenium(III) klorida dan [[Hidrazina|hidrazin]] hidrat:</div></td><td class="diff-marker" data-marker="+"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>Jika digunakan secara ''in situ'', kation dapat dibuat dengan mudah dari ruthenium(III) klorida dan [[Hidrazina|hidrazin]] hidrat:<ins style="font-weight: bold; text-decoration: none;"><ref>Allen, A. D., Bottomley, F., Harris, R. O., Reinsalu, V. P., Senoff, C. V. "Pentaammine(Nitrogen)Ruthenium(II) Salts and Other Ammines of Ruthenium" ''Inorganic Syntheses'', 2007, volume 12, pp. 2-8.</ref></ins></div></td></tr>
<tr><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>:RuCl<sub>3</sub> + 4 N<sub>2</sub>H<sub>4</sub> → [Ru(NH<sub>3</sub>)<sub>5</sub>N<sub>2</sub>]<sup>2+</sup> + ...</div></td><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>:RuCl<sub>3</sub> + 4 N<sub>2</sub>H<sub>4</sub> → [Ru(NH<sub>3</sub>)<sub>5</sub>N<sub>2</sub>]<sup>2+</sup> + ...</div></td></tr>
<tr><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><br></td><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><br></td></tr>
<tr><td class="diff-marker" data-marker="−"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div>Kompleks N<sub>2</sub> ini stabil dalam larutan akuatik dan memiliki tingkat pertukaran ligan yang relatif rendah dengan air. Sebagai kompleks d<sup>6</sup>, ikatan Ru-N distabilkan oleh [[ikatan balik Pi]], penyumbangan elektron-d dari logam ke orbital π* N<sub>2</sub>. Dikenal juga [[kompleks logam amina]] terkaitnya [Os(NH<sub>3</sub>)<sub>5</sub>(N<sub>2</sub>)]<sup>2+</sup>.</div></td><td class="diff-marker" data-marker="+"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>Kompleks N<sub>2</sub> ini stabil dalam larutan akuatik dan memiliki tingkat pertukaran ligan yang relatif rendah dengan air. Sebagai kompleks d<sup>6</sup>, ikatan Ru-N distabilkan oleh [[ikatan balik Pi]], penyumbangan elektron-d dari logam ke orbital π* N<sub>2</sub>.<ins style="font-weight: bold; text-decoration: none;"><ref>Taube, H. "Chemistry of Ruthenium(II) and Osmium(II) Ammines" ''Pure and Applied Chemistry'', 1979, volume 51, p. 901–12.</ref> </ins>Dikenal juga [[kompleks logam amina]] terkaitnya [Os(NH<sub>3</sub>)<sub>5</sub>(N<sub>2</sub>)]<sup>2+</sup>.</div></td></tr>
<tr><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><br></td><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><br></td></tr>
<tr><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>== Reaksi ==</div></td><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>== Reaksi ==</div></td></tr>
<tr><td class="diff-marker" data-marker="−"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div>Ligan dinitrogen tidak tereduksi menjadi larutan [[natrium borohidrida]]. Hampir seluruh reaksi senyawa ini yang diketahui adalah reaksi pemindahan. Pentaamina([[halogen]])ruthenium(II) halida dapat disintesis melalui perlakuan [Ru(NH<sub>3</sub>)<sub>5</sub>N<sub>2</sub>]<sup>2+</sup> dengan sumber halida:</div></td><td class="diff-marker" data-marker="+"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>Ligan dinitrogen tidak tereduksi menjadi larutan [[natrium borohidrida]].<ins style="font-weight: bold; text-decoration: none;"><ref>J. Chatt, R. L. Richards, J. F. Fergusson and J. L. Love, "The reduction of nitrogen complexes" ''Chem. Commun.'' 1968, 1522.</ref> </ins>Hampir seluruh reaksi senyawa ini yang diketahui adalah reaksi pemindahan. Pentaamina([[halogen]])ruthenium(II) halida dapat disintesis melalui perlakuan [Ru(NH<sub>3</sub>)<sub>5</sub>N<sub>2</sub>]<sup>2+</sup> dengan sumber halida:<ins style="font-weight: bold; text-decoration: none;"><ref>Allen, A. D., Bottomley, F., Harris, R. O., Reinsalu, V. P., Senoff, C. V. "Pentaammine(Nitrogen)Ruthenium(II) Salts and Other Ammines of Ruthenium" ''Inorganic Syntheses'', 2007, volume 12, pp. 2-8.</ref></ins></div></td></tr>
<tr><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>:[Ru(NH<sub>3</sub>)<sub>5</sub>N<sub>2</sub>]<sup>2+</sup> + X<sup>−</sup> → [Ru(NH<sub>3</sub>)<sub>5</sub>X]<sup>+</sup> + N<sub>2</sub></div></td><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>:[Ru(NH<sub>3</sub>)<sub>5</sub>N<sub>2</sub>]<sup>2+</sup> + X<sup>−</sup> → [Ru(NH<sub>3</sub>)<sub>5</sub>X]<sup>+</sup> + N<sub>2</sub></div></td></tr>
<tr><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><br></td><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><br></td></tr>
<tr><td class="diff-marker" data-marker="−"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div>[Ru(NH<sub>3</sub>)<sub>5</sub>N<sub>2</sub>]<sup>2+</sup> membentuk [[Kompleks dinitrogen logam transisi|kompleks dinitrogen]] simetris berjembatan simetris [(NH<sub>3</sub>)<sub>5</sub>Ru-NN-Ru(NH<sub>3</sub>)<sub>5</sub>]<sup>4+</sup>.</div></td><td class="diff-marker" data-marker="+"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div>[Ru(NH<sub>3</sub>)<sub>5</sub>N<sub>2</sub>]<sup>2+</sup> membentuk [[Kompleks dinitrogen logam transisi|kompleks dinitrogen]] simetris berjembatan simetris [(NH<sub>3</sub>)<sub>5</sub>Ru-NN-Ru(NH<sub>3</sub>)<sub>5</sub>]<sup>4+</sup>.<ins style="font-weight: bold; text-decoration: none;"><ref>D. F. Harrison, F. Weissberger and H. Taube, ''Science'', 1968, volume 159, 320.</ref><ref>Chatt, J. "Molecular Nitrogen as a Ligand" ''Pure Appl. Chem.'', 1970, volume 24, pp. 425–442.</ref></ins></div></td></tr>
<tr><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><br></td><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><br></td></tr>
<tr><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>== Referensi ==</div></td><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><div>== Referensi ==</div></td></tr>
<tr><td colspan="2" class="diff-side-deleted"></td><td class="diff-marker" data-marker="+"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div><ins style="font-weight: bold; text-decoration: none;"><references /></ins></div></td></tr>
<tr><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><br></td><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><br></td></tr>
<tr><td colspan="2" class="diff-side-deleted"></td><td class="diff-marker" data-marker="+"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div><ins style="font-weight: bold; text-decoration: none;">== Sumber dan atribusi ==</ins></div></td></tr>
<tr><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><br></td><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><br></td></tr>
<tr><td colspan="2" class="diff-side-deleted"></td><td class="diff-marker" data-marker="+"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div><ins style="font-weight: bold; text-decoration: none;">Konten artikel ini diadaptasi dari [https://id.wikipedia.org/w/index.php?title=Pentaamina%28dinitrogen%29rutenium%28II%29+klorida&oldid=26994809 Wikipedia bahasa Indonesia], revisi 26994809 (2025-03-04T23:30:50Z), yang tersedia berdasarkan lisensi Creative Commons Atribusi-BerbagiSerupa (CC BY-SA). Gambar pada artikel ini bersumber dari Wikimedia Commons dan mengikuti ketentuan lisensi masing-masing berkas. Mohon gunakan konten dan media secara bijak serta sesuai dengan ketentuan lisensi yang berlaku.</ins></div></td></tr>
<tr><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><br></td><td class="diff-marker"></td><td style="background-color: #f8f9fa; color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #eaecf0; vertical-align: top; white-space: pre-wrap;"><br></td></tr>
<tr><td class="diff-marker" data-marker="−"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;">== Sumber dan atribusi ==</del></div></td><td class="diff-marker" data-marker="+"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div><ins style="font-weight: bold; text-decoration: none;"><!</ins>-- <ins style="font-weight: bold; text-decoration: none;">WIKI_UNISSULA_PRESENTATION_V4 </ins>--<ins style="font-weight: bold; text-decoration: none;">></ins></div></td></tr>
<tr><td class="diff-marker" data-marker="−"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div> </div></td><td colspan="2" class="diff-side-added"></td></tr>
<tr><td class="diff-marker" data-marker="−"></td><td style="color: #202122; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;">Konten artikel ini diadaptasi dari [https://id.wikipedia.org/w/index.php?title=Pentaamina%28dinitrogen%29rutenium%28II%29+klorida&oldid=26994809 Wikipedia bahasa Indonesia], revisi 26994809 (2025</del>-<del style="font-weight: bold; text-decoration: none;">03</del>-<del style="font-weight: bold; text-decoration: none;">04T23:30:50Z), yang tersedia berdasarkan lisensi Creative Commons Atribusi</del>-<del style="font-weight: bold; text-decoration: none;">BerbagiSerupa (CC BY</del>-<del style="font-weight: bold; text-decoration: none;">SA). Mohon gunakan konten ini secara bijak serta sesuai dengan ketentuan lisensi yang berlaku.</del></div></td><td colspan="2" class="diff-side-added"></td></tr>
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Maintenance script: Impor teks terkontrol dari Wikipedia bahasa Indonesia; revisi 26994809; atribusi sumber disertakan.
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<p>Impor teks terkontrol dari Wikipedia bahasa Indonesia; revisi 26994809; atribusi sumber disertakan.</p>
<p><b>Halaman baru</b></p><div>'''Pentaamina(dinitrogen)rutenium(II)''' klorida adalah suatu [[senyawa anorganik]] dengan rumus [Ru(NH<sub>3</sub>)<sub>5</sub>(N<sub>2</sub>)]Cl<sub>2</sub>. Ia berupa padatan hampir putih, tetapi larutannya berwarna kuning. Kompleks kationnya memiliki makna historis sebagai senyawa pertama dengan N terikat pada pusat logam. [Ru(NH<sub>3</sub>)<sub>5</sub>(N<sub>2</sub>)]<sup>2+</sup> mengadopsi struktur oktahedral dengan simeteri C<sub>4v</sub>.<br />
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== Preparasi dan sifat ==<br />
Pentaamine(nitrogen)ruthenium(II) klorida disintesis dalam larutan air dari pentaaminaklororuthenium(III) klorida, [[natrium azida]], dan [[asam metanasulfonat]]:<br />
:[Ru(NH<sub>3</sub>)<sub>5</sub>Cl]Cl<sub>2</sub> + NaN<sub>3</sub> → [Ru(NH<sub>3</sub>)<sub>5</sub>N<sub>2</sub>]Cl<sub>2</sub> + ...<br />
Jika digunakan secara ''in situ'', kation dapat dibuat dengan mudah dari ruthenium(III) klorida dan [[Hidrazina|hidrazin]] hidrat:<br />
:RuCl<sub>3</sub> + 4 N<sub>2</sub>H<sub>4</sub> → [Ru(NH<sub>3</sub>)<sub>5</sub>N<sub>2</sub>]<sup>2+</sup> + ...<br />
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Kompleks N<sub>2</sub> ini stabil dalam larutan akuatik dan memiliki tingkat pertukaran ligan yang relatif rendah dengan air. Sebagai kompleks d<sup>6</sup>, ikatan Ru-N distabilkan oleh [[ikatan balik Pi]], penyumbangan elektron-d dari logam ke orbital π* N<sub>2</sub>. Dikenal juga [[kompleks logam amina]] terkaitnya [Os(NH<sub>3</sub>)<sub>5</sub>(N<sub>2</sub>)]<sup>2+</sup>.<br />
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== Reaksi ==<br />
Ligan dinitrogen tidak tereduksi menjadi larutan [[natrium borohidrida]]. Hampir seluruh reaksi senyawa ini yang diketahui adalah reaksi pemindahan. Pentaamina([[halogen]])ruthenium(II) halida dapat disintesis melalui perlakuan [Ru(NH<sub>3</sub>)<sub>5</sub>N<sub>2</sub>]<sup>2+</sup> dengan sumber halida:<br />
:[Ru(NH<sub>3</sub>)<sub>5</sub>N<sub>2</sub>]<sup>2+</sup> + X<sup>−</sup> → [Ru(NH<sub>3</sub>)<sub>5</sub>X]<sup>+</sup> + N<sub>2</sub><br />
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[Ru(NH<sub>3</sub>)<sub>5</sub>N<sub>2</sub>]<sup>2+</sup> membentuk [[Kompleks dinitrogen logam transisi|kompleks dinitrogen]] simetris berjembatan simetris [(NH<sub>3</sub>)<sub>5</sub>Ru-NN-Ru(NH<sub>3</sub>)<sub>5</sub>]<sup>4+</sup>.<br />
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== Referensi ==<br />
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== Sumber dan atribusi ==<br />
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Konten artikel ini diadaptasi dari [https://id.wikipedia.org/w/index.php?title=Pentaamina%28dinitrogen%29rutenium%28II%29+klorida&oldid=26994809 Wikipedia bahasa Indonesia], revisi 26994809 (2025-03-04T23:30:50Z), yang tersedia berdasarkan lisensi Creative Commons Atribusi-BerbagiSerupa (CC BY-SA). Mohon gunakan konten ini secara bijak serta sesuai dengan ketentuan lisensi yang berlaku.</div>
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